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H C N C Thiamine pyrophosphate S C (TPP) N C H C S C CC CC Resonance OC OC OC OC Resonance H C OH R1 Fructose 6-phosphate (sedoheptulose 7-phosphate) H C OH R1 H C OH R2 H C OH R2 Xylulose 5-phosphate Transfer of C2-unit bound to TPP CNC CNC CNC HOC C H C OH R1 HOCC HOC C SCSCSC H C OH R2 TPP-adduct TPP-adduct H C OH R1 H C OH R2 HH HO HO CC R1 Erythrose 4-phosphate (ribose 5-phosphate) R2 D-Glyceraldehyde 3-phosphate Figure 6.

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